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has food value. Olive oil is slightly laxative and assists mechanically in the digestion of foods.

68. Figs.—Dried figs contain about 50 per cent of sugar and 3.5 per cent of protein. The fig has a mildly laxative action.

69. Dried Fruits.—Many fruits are prepared for market by drying. The dried fruit has a slightly different composition from the fresh fruit because of loss of the volatile and essential oils, and minor chemical changes which take place during the drying process. When free from preservatives, dried fruits are valuable adjuncts to the dietary and can be advantageously used when fresh fruits are not obtainable.

70. Canning and Preservation of Fruits.—To obtain the best results in canning, the fruit should not be overripe. After the ripened state has been reached fermentation and bacterial changes occur, and it is more difficult to preserve the fruit than when not so fully matured.[24] When a fruit has begun to ferment, it is hard to destroy the ferment bodies and their spores so as to prevent further ferment action. The chemical changes that occur in the last stages of ripening are similar to those which take place during the cooking process whereby the pectin or jelly-like substances are rendered more soluble and digestible.

71. Adulterated Canned Fruits.—Analyses of a number of canned fruits, made by various Boards of Health, show the presence of small amounts of arsenic, tin, lead, and other poisonous metals. The quantity dissolved depends upon the kind, age, and condition of the canned goods and the state of the fruit when canned. The longer a can of fruit or vegetable has been kept in stock, the larger is the amount of tin or metal that has been dissolved. When fresh canned, there is usually very little dissolved tin, but in old goods the amount may be comparatively large. The tin used for the can is occasionally of poor quality and may contain some arsenic, which also is dissolved. The occasional use of canned goods preserved in tin is not objectionable, but they should not be used continually if it can be avoided. Preservatives, as borax, salicylic acid, benzoic acid, and sodium sulphate, are sometimes added to prevent fermentation and to preserve the natural appearance of the fruit or vegetable.[18]

72. Fruit Flavors and Extracts.—Formerly all fruit extracts and flavors were obtained from vegetable sources; at present many are made in the chemical laboratory by synthetic methods; that is, by combining simpler organic compounds and radicals to produce the material having the desired flavor and odor. The various fruit flavors are definite chemical compounds, and can be produced in the laboratory as well as in the cells of plants. When properly made, there is no difference in chemical composition between the two. As prepared in the laboratory, however, traces of acids, alkalies, and other compounds, used in bringing about the necessary chemical combination, are often present, not having been perfectly removed. Hence it is that natural and artificial flavors differ mainly in the impurities which the artificial flavors may contain.

Some of the flavoring materials have characteristic medicinal properties, as the flavor of bitter almond, which contains hydrocyanic acid, a poisonous substance. Flavors and extracts should not be indiscriminately used. In small amounts they often exert a favorable influence upon the digestion of foods, and the value of some fruits is in a large measure due to the special flavors they contain. A study of the separate compounds which impart flavor to fruits, as the various aldehydes, ethers, and organic salts, belongs to organic chemistry rather than to foods. Some of the simpler compounds of which flavors are composed may exist in entirely different form or combination in food products; as for example, pineapple flavoring is ethyl butrate. This can be prepared by combination of butyric acid from stale butter with alcohol which supplies the ethyl radical. The chemical union of the two produces the new compound, ethyl butrate, the distinctive flavoring substance of the pineapple. Banana flavor can be made from stale butter, caustic soda, and chloroform. None of these materials, as such, go into the flavor, but an essential radical is taken from each. These manufactured products, when properly made, are in every essential similar to the flavor made by the plant and stored up in the fruit. The plant combines the material in the laboratory of the plant cell, and the manufacturer of essences puts together these same constituents in a chemical laboratory. In the fruit, however, the essential oil is associated with a number of other compounds.

CHAPTER V SUGARS, MOLASSES, SYRUP, HONEY, AND CONFECTIONS

73. Composition of Sugars.—The term "sugar" is applied to a large class of compounds composed of the elements carbon, hydrogen, and oxygen. Sugars used for household purposes are derived mainly from the sugar cane and the sugar beet.[25] At the present time about two fifths are obtained from the cane and about three fifths from the beet. When subjected to the same degree of refining, there is no difference in the chemical composition of the sugars from the two sources; they are alike in every respect and the chemist is unable to determine their origin. The production of sugar is an agricultural industry; the methods of manufacture pertain more to industrial chemistry than to the chemistry of foods, and therefore a discussion of them is omitted in this work.[26]

Fig. 15.
Fig. 15.—Sugar Crystals.

74. Commercial Grades of Sugar.—Sugars are graded according to the size of the granule, the color and general appearance of the crystals, and the per cent of sucrose or pure sugar. Common granulated sugar is from 98.5 to 99.7 per cent pure sucrose. The impurities consist mainly of moisture and mineral matter. In the process of refining, sulphur fumes are frequently used for bleaching and clarifying the solution.[26] The sulphurous acid formed is neutralized with lime, which is rendered insoluble and practically all removed in subsequent filtrations. There are, however, traces of sulphates and sulphites in ordinary sugar, but these are in such small amounts as not to be injurious to health. When sugar is burned, as in the bomb calorimeter, so as to permit collection of all of the products of combustion, granulated sugar yields about 0.01 of a per cent of sulphur dioxid.[13] Occasionally coloring substances, as a small amount of indigo, are added to yellow tinged sugars to impart a white color, much on the same principle as the bluing of clothes. The amount used is usually extremely small, and the effect on health has never been determined. Occasionally, however, bluing is used to such an extent that a blue scum appears when the sugar is boiled with water. Sugar has high value for the production of heat and energy. Digestion experiments show that when it is used in the dietary in not excessive amounts, it is directly absorbed by the body and practically all available. It can advantageously be combined with other foods to form a part of the ration.[27] When a ration contains the requisite amount of protein, sugar is used to the best advantage. Alone it is incapable of sustaining life, because it does not contain any nitrogen. When sugar was substituted for an excess of protein in a ration, it was found to produce heat and energy at much less expense. Many foods, as apples, grapes, and small fruits, contain appreciable amounts of sugar and owe their food value almost entirely to their sugar content. In the dietary, sugar is too frequently regarded as a condiment instead of a nutrient, to be used for imparting palatability rather than for purposes of nutrition. While valuable for improving the taste of foods, the main worth of sugar is as a nutritive substance; used in the preparation of foods it adds to the total heat and energy of the ration. Sugar is sometimes used in excessive amounts and, as is the case with any food or nutrient, when that occurs, nutrition disturbances result, due to misuse of the food. Statistics show that the average consumption of sugar in the United States is nearly 70 pounds a year per capita. In the dietary of the adult, sugar to the extent of four ounces per day can be consumed advantageously. The exclusion of sugar from the diet of children is a great mistake, as they need it for heat and energy and to conserve the protein for growth.

"Sugar is one of the most important forms in which carbohydrates can be added to the diet of children. The great reduction in the price of sugar which has taken place in recent years is probably one of the causes of the improved physique of the rising generation. The fear that sugar may injure children's teeth is, largely illusory. The negroes who live largely on sugar cane have the finest teeth the world can show. If injudiciously taken, sugar may, however, injure the child's appetite and digestion. The craving for sweets which children show is no doubt the natural expression of a physiological need, but they should be taken with, and not between, meals."[28]

Fig. 16.
Fig. 16.—Nutrients of a Ration With Sugar.
The hacket parts represent the proportion of nutrients not digested.

75. Sugar in the Dietary.—Sugar has an important place in the dietary. It not only serves for the production of heat and energy in the body, but is also valuable in enabling the proteids to be used more economically. In reasonable amounts, it is particularly valuable in the dietary of growing children, as the proteids of the food are then utilized to better advantage for growth. The unique value of sugar depends upon its intelligent use and its proper combination with other foods, particularly with those rich in the nitrogenous compounds or proteids. Sugar alone is incapable of sustaining life, but combined with other foods is a valuable nutrient. The amount which can be advantageously used depends largely upon the individual. Ordinarily three to five ounces per day is sufficient, although some persons cannot safely consume as much as this. In the case of diabetes mellitus, the amount of sugar in the ration must be materially reduced. Persons in normal health and engaged in outdoor work can use sugar to advantage.[29] Many of the "harvest drinks," made largely from molasses with a little ginger, and used extensively in some localities, are not without merit, as they contain an appreciable amount of nutrients. Milk contains more sugar as lactose or milk sugar than any other nutrient.

Fig. 17.
Fig. 17.—Nutrients of a Ration Without Sugar.
The hacket parts represent the proportion of nutrients not digested.

The craving for sugar by growing children and athletes is natural. Sugar, however, is often injudiciously used, and a perverted taste may be established which can be satisfied only by excessive amounts. This results in impaired digestion and malnutrition.

76. Maple Sugar.—Sugar obtained by evaporation from the sap of the maple tree (Acer saccharinum) is identical, except for the foreign substances which it contains, with that from the beet and sugar cane. The mottled appearance and characteristic color and taste of maple sugar are due to the various organic acids and other compounds present in the maple sap and recovered in the sugar. Maple sugar, as ordinarily prepared, has 0.4 of a per cent or more of ash or mineral matter, while refined cane sugar contains less than one tenth as much.[30] Hence, when maple sugar is adulterated with cane and beet sugars, the ash content is noticeably lowered, as is also the content of organic acids. It is difficult, however, to

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