Human Foods and Their Nutritive Value - Harry Snyder (e book reader pc TXT) 📗
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77. Adulteration of Sugar.—Sugar at the present time is not materially adulterated. Other than the substances mentioned which are used for clarification and color, none are added during refining which remain in the sugar in appreciable amounts. Sugar does not readily lend itself to adulteration, as it has a definite crystalline structure, and materials that would be suitable for its adulteration are of entirely different physical character.[31] Cane sugar is not easily blended with glucose, or starch sugar, because of the physical differences between the two. The question of the kind of sugar to use in the household, as granulated, loaf, or pulverized, is largely one of personal choice, as there is no appreciable difference in the nutritive value or purity of the different kinds.
78. Dextrose Sugars.—Products known as glucose and dextrose sugars are made from corn and other starches; they can also be prepared from cane sugar by the use of heat, chemicals, or ferments for carrying on the process known as inversion. The dextrose sugars differ from cane sugar in containing a dissimilar number of carbon, hydrogen, and oxygen atoms in the molecule. The formula of the dextrose sugars is C6H12O6, while that of cane sugar is C12H22O11. By the addition of one molecule of water, H2O, to a molecule of sucrose, two molecules of invert sugar (dextrose and glucose) are produced:[1] C12H22O11 + H2 = C6H12O6 + C6H12O6. In bringing about this change, acids are employed, but the acid in no way enters into the chemical composition of the final product; it is removed as described during the process of sugar manufacture. The action of the acid brings about a catalytic change, the acid being necessary only as a presence reagent to start the chemical reaction. When properly prepared and the acid product thoroughly removed, dextrose and glucose have practically the same food value as sugar. When they are digested, heat and energy are produced, and a given weight has about the same fuel value as an equal weight of sugar. Some of the glucose-yielding products can be made at less expense than sugar, and when they are sold under their right names there is no reason why they should not be used in the dietary, as they serve the same nutritive purpose.
79. Molasses is a by-product obtained in the refining of sugar. It is a mixture of cane sugar and invert sugars, as levulose and dextrose. When in sugar making the sucrose is removed by crystallization, a point is finally reached where the solution, or mother liquid, as it is called, refuses to give up any further crystals;[31] then this product, consisting of various sugars and small amounts of organic acids and ash, is partially refined and clarified to form molasses. The term "New Orleans" molasses was formerly applied to the product obtained by the use of open kettles for the manufacture of sugar, but during recent years the vacuum pan process has been introduced, and "New Orleans" molasses is now an entirely different article. The terms first, second, and third molasses are applied to the liquids obtained after the removal of the first, second, and third crops of sugar crystals; first molasses being richer in sucrose, while third molasses is richer in dextrose and invert sugars. The ash in molasses ranges from 4 to 6.5 per cent. Some of the low grades of molasses are used in the preparation of animal foods.
The taste and physical characteristics of molasses are due largely to the organic acids and impurities that are present, as well as to the proportion in which the various sugars occur. When used with soda in cooking and baking operations, the organic acid of the molasses liberates carbon dioxide gas, which acts as a leavening agent. Because of the organic acids, molasses should not be stored in tin or metalware dishes, as the solvent action results in producing poisonous tin and other metallic salts.
The food value of molasses is dependent entirely upon the amount of dry matter and the per cent of sugar. A large amount of water is considered an adulterant; ordinarily molasses contains from 20 to 33 per cent. If a sample of molasses contains 75 per cent of dry matter, it has slightly less than three fourths of the nutritive value of the same weight of sugar.
Fig. 18.—Graphic
Composition of Syrup.
80. Syrups.—The term "syrup" is applied to natural products obtained by evaporation and purification of the saccharine juices of plants. Sorghum syrup is from the sorghum plant, which is pressed by machinery and the juice clarified and evaporated so as to contain about 25 per cent of water. In sorghum syrups there are from 30 to 45 per cent of cane sugar, and from 12 to 20 per cent of glucose and invert sugars. Cane syrup is made from the clarified juice of the sugar cane, and has about the same general composition as sorghum syrup. Maple syrup, prepared from the juice of the sugar maple, is characteristically rich in sucrose and contains but little glucose or reducing sugars. The flavor of all the syrups is due mainly to organic acids, ethereal products, and impurities. In some instances the essential flavor can be produced synthetically, or derived from other and cheaper materials; and by the use of these flavors, mixed syrups can be prepared closely resembling many of the natural products. When properly made, they are equal in nutritive value to natural syrups. When sold under assumed names, they are to be considered and classified as adulterated, and not as syrups from definite and specific products. Low-grade syrups and molasses are often used for making fuel alcohol. They readily undergo alcoholic fermentation and are valuable for this purpose, rendering it possible for a good grade of fuel alcohol to be produced at low cost. The manufacture of sugar, syrups, and molasses has been brought to a high degree of perfection through the assistance rendered by industrial chemistry. Losses in the process are reduced to a minimum, and the various steps are all controlled by chemical analysis. Sugar has the physical property of deflecting a ray of polarized light, the amount of deflection depending upon the quantity of sugar in solution. This is measured by the polariscope, an instrument by means of which the sugar content of sugar plants is rapidly determined.
81. Honey is composed largely of invert sugars gathered by the honeybee from the nectar of flowers. It varies in composition and flavor according to its source. The color depends upon the flower from which it came, white clover giving a light-colored, pleasant-flavored honey, while that from buckwheat and goldenrod is dark and has a slightly rank taste. The comb is composed largely of wax, which has somewhat the same general composition as fat, but contains ethereal instead of glycerol bodies. On account of the predominance of invert sugars, pure honey has a levulo or left-handed rotation when examined by the polariscope. Honey contains from 60 to 75 per cent of invert sugars, and from 12 to 20 per cent of water, while the ash content is small, less than one tenth of one per cent. Strained honey is easily adulterated with glucose products. Adulteration with cane sugar is readily detected, as pure honey contains only a very small amount of sucrose. Honey can be made by feeding bees on sugar; the sugar undergoes inversion, with the production of dextrose. Such honey, although not adulterated, is inferior in quality and lacking in natural flavor.[18]
82. Confections.—By blending various saccharine products, confections are made. Usually sucrose (cane and beet sugar) is used as the basis for their preparation. Sucrose has definite physical properties, as crystalline structure, and forms chemical and mechanical combinations with acid, alkaline, and other substances; it also unites with water, and when heated undergoes changes in structural composition. The presence of small amounts of acid substances, or variations in the concentration of the sugar solution, materially affect the mechanical relation of the sugar particles to each other, and their crystallization. Usually crystallization takes place when there is less than 25 per cent of water present. The form, size, and arrangement of the crystals are influenced by agitation during cooling. To secure desired results, often small quantities of various other substances are employed for their mechanical action. Glucose is frequently used, and is said to be necessary for the production of some kinds of candy.
Candies are colored with various dyes and pigments, many of which are harmless, although some are injurious. Coal tar dyes are frequently employed for this purpose. Objection has generally been urged against their use, as it is believed many of them are injurious to health. It cannot be said, however, that all are poisonous, as some are known to be harmless. The use of a few coal tar dyes is allowed by the United States government. Mineral colors are now rarely, if ever, used.
Impure candies result from objectionable ingredients, as starch, paraffin, and large amounts of injurious coloring substances. Coal tar coloring materials are identified in the way described in Experiment No. 13. Confectionery, when properly prepared and unadulterated, has the same nutritive value as sugar and the other ingredients, and is entitled to a place in the dietary for the production of heat and energy. Much larger amounts of candies are sold and consumed during the winter than the summer months, suggesting that in cold weather candy is most needed in the dietary.
83. Saccharine is an artificial sweetening, five hundred times sweeter than cane sugar. It contains in its molecule, chemically united, benzine, sulphuric acid, and ammonia radicals. It is employed for sweetening purposes in cases of diabetes mellitus, where physicians advise against the use of sugar. It has no food value. A small amount is sometimes added to canned corn and tomatoes to impart a sweet taste. The physiological properties of saccharine have not been extensively investigated.
CHAPTER VI LEGUMES AND NUTS84. General Composition of Legumes.—Peas, beans, lentils, and peanuts are the legumes most generally used for human food. As a class, they are characterized by high protein content and a comparatively low per cent of starch and carbohydrates. They contain the largest amount of nitrogenous compounds of any of the vegetable foods, and hence are particularly valuable in the human ration as a substitute for meats.[32] For feeding animals the legumes are highly prized, particularly the forage crops, clover and alfalfa. These secure their nitrogen, which is the characteristic element of protein, from the free nitrogen of the air, through the workings of bacterial organisms found in the nodules on the roots of the plants. The legumes appear to be the only plants capable of making use of the nitrogen of the air for food purposes.
85. Beans contain about 24 per cent of protein and but little fat, less than is found in any of the grain or cereal products. The protein of the bean differs from that of cereals in its general and structural composition. It is a globulin known as legumin, and is acted upon mainly by ferments working in alkaline solutions, as in the lower part of the digestive tract. Beans have about the same amount of ash as the cereals, but the ash is richer in potash and lime.
Fig. 19.—Graphic
Composition of Beans.
Hacked Part Indigestible.
86. Digestibility of Beans.—Beans are usually considered indigestible, but experiments show they are quite completely digested, although they require more work on the part of the digestive tract than many other foods. The digestibility was found
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