The Art of Perfumery - George William Septimus Piesse (most read books in the world of all time txt) 📗
- Author: George William Septimus Piesse
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Six years ago I began making a series of medicated soaps, such as Sulphur Soap, Iodine Soap, Bromine Soap, Creosote Soap, Mercurial Soap, Croton Oil Soap, and many others. These soaps are prepared by adding the medicant to curd soap, and then making in a tablet form for use. For sulphur soap, the curd soap may be melted, and flowers of sulphur added while the soap is in a soft condition. For antimony soap and mercurial soap, the low oxides of the metals employed may also be mixed in the curd soap in a melted state. Iodine, bromine, creosote soap, and others containing very volatile substances, are best prepared cold by shaving up the curd soap in a mortar, and mixing the medicant with it by long beating.
In certain cutaneous diseases the author has reason to believe that they will prove of infinite service as auxiliaries to the general treatment. It is obvious that the absorbent vessels of the skin are very active during the lavoratory process; such soap must not, therefore, be used except by the special advice of a medical man. Probably these soaps will be found useful for internal application. The precedent of the use of Castile soap (containing oxide of iron) renders it likely that when prejudice has passed away, such soaps will find a place in the pharmacopœias. The discovery of the solubility, under certain conditions, of the active alkaloids, quinine, morphia, &c., in oil, by Mr. W. Bastick, greatly favors the supposition of analogous compounds in soap.
SECTION IX. EMULSINES.From soaps proper we now pass to those compounds used as substitutes for soap, which are classed together under one general title as above, for the reason that all cosmetiques herein embraced have the property of forming emulsions with water.
Chemically considered, they are an exceedingly interesting class of compounds, and are well worthy of study. Being prone to decomposition, as might be expected from their composition, they should be made only in small portions, or, at least, only in quantities to meet a ready sale.
While in stock they should be kept as cool as possible, and free from a damp atmosphere.
Amandine.Rub the syrup with the soft soap until the mixture is homogeneous, then rub in the oil by degrees; the perfume having been previously mixed with the oil.
In the manufacture of amandine (and olivine) the difficulty is to get in the quantity of oil indicated, without which it does not assume that transparent jelly appearance which good amandine should have. To attain this end, the oil is put into "a runner," that is, a tin or glass vessel, at the bottom of which is a small faucet and spigot, or tap. The oil being put into this vessel is allowed to run slowly into the mortar in which the amandine is being made, just as fast as the maker finds that he can incorporate it with the paste of soap and syrup; and so long as this takes place, the result will always have a jelly texture to the hand. If, however, the oil be put into the mortar quicker than the workman can blend it with the paste, then the paste becomes "oiled," and may be considered as "done for," unless, indeed, the whole process be gone through again, starting off with fresh syrup and soap, using up the greasy mass as if it were pure oil. This liability to "go off," increases as the amandine nears the finish; hence extra caution and plenty of "elbow grease" must be used during the addition of the last two pounds of oil. If the oil be not perfectly fresh, or if the temperature of the atmosphere be above the average of summer heat, it will be almost impossible to get the whole of the oil given in the formula into combination; when the mass becomes bright and of a crystalline lustre, it will be well to stop the further addition of oil to it.
This and similar compounds should be potted as quickly as made, and the lids of the pots banded either with strips of tin-foil or paper, to exclude air. When the amandine is filled into the jars, the top or face of it is marked or ornamented with a tool made to the size of half the diameter of the interior of the jar, in a similar way to a saw; a piece of lead or tortoise-shell, being serrated with an angular file, or piece of an "old saw," will do very well; place the marker on the amandine, and turn the jar gently round.
Olivine.Rub the gum and honey together until incorporated, then add the soap and egg. Having mixed the green oil and perfumes with the olive oil, the mixture is to be placed in the runner, and the process followed exactly as indicated for amandine.
Honey and Almond Paste. (Pâte d'Amande au Miel.)Rub the eggs and honey together first, then gradually add the oil, and finally the ground almonds and the perfume.
Almond Paste.Place the ground almonds and one pint of the rose-water into a stewpan; with a slow and steady heat, cook the almonds until their granular texture assumes a pasty form, constantly stirring the mixture during the whole time, otherwise the almonds quickly burn to the bottom of the pan, and impart to the whole an empyreumatic odor.
The large quantity of otto of almonds which is volatilized during the process, renders it essential that the operator should avoid the vapor as much as possible.
When the almonds are nearly cooked, the remaining water is to be added; finally the paste is put into a mortar, and well rubbed with the pestle; then the perfume and spirit are added. Before potting this paste, as well as honey paste, it should be passed through a medium fine sieve, to insure uniformity of texture, especially as almonds do not grind kindly.
Other pastes, such as Pâte de Pistache, Pâte de Cocos, Pâte de Guimauve, are prepared in so similar a manner to the above that it is unnecessary to say more about them here, than that they must not be confounded with preparations bearing a similar name made by confectioners.
Almond Meal.Other meals, such as perfumed oatmeal, perfumed bran, &c., are occasionally in demand, and are prepared as the foregoing.
All the preceding preparations are used in the lavatory process as substitutes for soap, and to "render the skin pliant, soft, and fair!"
Emulsin au Jasmin.Emulsin of other odors can be prepared with tubereuse, rose, or cassie (acacia) oil (prepared by enfleurage or maceration).
For the methods of mixing the ingredients, see "Amandine," p. 195.
On account of the high price of the French oils, these preparations are expensive, but they are undoubtedly the most exquisite of cosmetiques.
SECTION X. MILK, OR EMULSIONS.In the perfumery trade, few articles meet with a more ready sale than that class of cosmetiques denominated milks. It has long been known that nearly all the seeds of plants which are called nuts, when decorticated and freed from their pellicle, on being reduced to a pulpy mass, and rubbed with about four times their weight of water, produce fluid which has every analogy to cow's milk. The milky appearance of these emulsions is due to the minute mechanical division of the oil derived from the nuts being diffused through the water. All these emulsions possess great chemical interest on account of their rapid decomposition, and the products emanating from their fermentation, especially that made with sweet almonds and pistachios (Pistachia vera).
In the manufacture of various milks for sale, careful manipulation is of the utmost importance, otherwise these emulsions "will not keep;" hence more loss than profit.
"Transformation takes place in the elements of vegetable caseine (existing in seeds) from the very moment that sweet almonds are converted into almond-milk."—Liebig. This accounts for the difficulty many persons find in making milk of almonds that does not spontaneously divide, a day or so after its manufacture.
Milk of Roses.Manipulation.—Shave up the soap, and place it in a vessel that can be heated by steam or water-bath; add to it two or three ounces of rose-water. When the soap is perfectly melted, add the wax and spermaceti, without dividing them more than is necessary to obtain the correct weight; this insures their melting slowly, and allows time for their partial saponification by the fluid soap; occasional stirring is necessary. While this is going on, blanch the almonds, carefully excluding every particle that is in the least way damaged. Now proceed to beat up the almonds in a scrupulously clean mortar, allowing the rose-water to trickle into the mass by degrees; the runner, as used for the oil in the manufacture of olivine, is very convenient for this purpose. When the emulsion of almonds is thus finished, it is to be strained, without pressure, through clean washed muslin (new muslin often contains starch, flour, gum, or dextrine).
The previously-formed saponaceous mixture is now to be placed in the mortar, and the ready-formed emulsion in the runner; the soapy compound and the emulsion is then carefully blended together. As the last of the emulsion runs into the mortar, the spirit, in which the otto of roses has been dissolved, is to take its place, and to be gradually trickled into the other ingredients. A too sudden addition of the spirit frequently coagulates the milk and causes it to be curdled; as it is, the temperature of the mixture rises, and every means must be taken to keep it down; the constant agitation and cold mortar effecting that object pretty well. Finally, the now formed milk of roses is to be strained.
The almond residue may be washed with a few ounces of fresh rose-water, in order to prevent any loss in bulk to the whole given quantity. The newly-formed milk should be placed into a bottle having a tap in it about a quarter of an inch from the bottom. After standing perfectly quiet for twenty-four hours it is fit to bottle. All
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